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Scheda pubblicazione
Titolo:
Class-modeling approach to PTR-TOFMS data: a peppers case study
Autori:
Taiti, C.; Costa, C.; Menesatti, P.; Comparini, D.; Bazihizina, N.; Azzarello, E.; Masi, E.; Mancuso, S.
Anno:
2015
Lingue:
ENG, eng
Rivista:
Journal of the Science of Food and Agriculture
Tipo di pubblicazione:
Cartaceo
Luogo:
Sussex
Editore:
John Wiley & Sons
Riassunto in Italiano:
Riassunto in Inglese:
BACKGROUND: Proton transfer reaction–mass spectrometry (PTR-MS), in its recently developed implementation based on time-of-flight mass spectrometry (PTR-TOFMS), was used to rapidly determine the volatile compounds present in fruits of Capsicum spp. RESULTS: We analyzed the volatile organic compounds emission profile of freshly cut chili peppers belonging to three species and 33 different cultivars. PTR-TOFMS data, analyzed with appropriate and advanced multivariate class-modeling approaches, perfectly discriminated among the three species (100% correct classification in validation set). VIP (variable importance in projection) scores were used to select the 15 most important volatile compounds in discriminating the species. The best candidates for Capsicum spp. were compounds with measured m/z of 63.027, 101.096 and 107.050, which were, respectively, tentatively identified as dimethyl sulfide, hexanal and benzaldehyde. CONCLUSIONS: Based on the promising results, the possibility of introducing multivariate class-modeling techniques, different from the classification approaches, in the field of volatile compounds analyses is discussed.
Link:
http://dx.doi.org/10.1002/jsfa.6761

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